Synthesis of 1,2-bis(1,4,7,10-tetra-azadodecanyl)ethane, a double-ring fully saturated macrocycle containing 12-membered tetra-aza subunits
- 1 January 1984
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 15,p. 998-999
- https://doi.org/10.1039/c39840000998
Abstract
The title compound, a fully saturated bimacrocycle (1), has been obtained through a procedure involving the protection of all but one of the amino nitrogen atoms of each tetra-aza ring which are then bridged by an ethylenic segment; (1) behaves as a dinucleating ligand, forming a dicopper(II) complex in which there is a weak ferromagnetic interaction between the metal atoms.Keywords
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