Stereochemistry of cleavage of silicon–platinum bonds in optically active silicon–platinum compounds
- 1 January 1972
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 22,p. 1223-1224
- https://doi.org/10.1039/c39720001223
Abstract
The cleavage of the Si–Pt bond in trans-(+)-[PtCl(*SiR3)(PPhMe2)2][R3Si*= MePh(1-naphthyl)Si] by LiAlH4, PhSH, or Et3SiH, and of that in (–)-[PtH(*SiR3)(PPh3)2] by LiAlH4, PhCOCl, PhCCH, or PhSH occurs with predominant retention of configuration at silicon.Keywords
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