An extraordinary isotope effect in a carbene rearrangement
- 21 July 1992
- journal article
- Published by Elsevier in Tetrahedron Letters
- Vol. 33 (30) , 4287-4290
- https://doi.org/10.1016/s0040-4039(00)74240-7
Abstract
No abstract availableThis publication has 14 references indexed in Scilit:
- Kinetics of alkylhalocarbene rearrangements: modulation by fluorine substituentsJournal of the American Chemical Society, 1992
- Contributions of quantum mechanical tunneling to the rate of benzylic hydrogen atom abstraction reactions of triplet diarylcarbenes in fluid solutionThe Journal of Physical Chemistry, 1991
- Kinetics of a 1,3-CH carbene insertion reaction: tert-butylchlorocarbeneJournal of the American Chemical Society, 1990
- Benzylchlorocarbene: kinetic parameters for 1,2-hydrogen migration, UV absorption spectrum, and mechanism for addition to alkenesJournal of the American Chemical Society, 1990
- The 1,2-hydrogen-shift rearrangement in alkylchlorocarbenesJournal of the American Chemical Society, 1989
- Thermolysis and photolysis of 3-chloro-3-benzyldiazirines in alkenes; evidence for a carbene-alkene complexThe Journal of Organic Chemistry, 1987
- Photolysis of 3-chlorodiazirine in the presence of alkenes. Kinetic evidence for intervention of a carbene-alkene intermediate in addition of chlorocarbene to alkeneJournal of the American Chemical Society, 1984
- Observations on the geometry of hydrogen transfer in [1,5] sigmatropic rearrangementsJournal of the American Chemical Society, 1982
- Pull-push mechanism for the 1,2-hydrogen rearrangement of carbenes. Substituent and deuterium isotope effects for thermal decomposition of 1-phenyl-2-diazopropanesJournal of the American Chemical Society, 1978
- Neopentyl displacement without rearrangementJournal of the American Chemical Society, 1972