Mechanism of the baeyer–villiger reaction
- 1 January 1970
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society D: Chemical Communications
- No. 20,p. 1301-1302
- https://doi.org/10.1039/c29700001301
Abstract
Examination of the effects of substituents on the rate and the migratory aptitude in the oxidation of substituted pp′-dimethoxybenzophenones with peroxy-benzoic acid in dichloroacetic acid to give aryl benzoates suggests that the rearrangement of peroxybenzoic acid—ketone adducts to esters is rate-determing.Keywords
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