Cyclopolymerization. III. Electron Spin Resonance Studies of Diallylamines with Redox Systems
- 1 January 1975
- journal article
- research article
- Published by Taylor & Francis in Journal of Macromolecular Science: Part A - Chemistry
- Vol. 9 (1) , 125-147
- https://doi.org/10.1080/00222337508068651
Abstract
The reaction of a series of diallylamines and related compounds with free radicals in aqueous acid solution has been studied in a flow system using ESR spectroscopy. The initiation was by radicals generated from titanium trichloride-hydrogen peroxide (hydroxyl radicals) and titanium trichloride-hydroxylamine (amino radicals) systems, respectively. The observed ESR spectra were assigned to five-membered ring radicals as the major radical species present in the system. However, the dimethallyl-amine series gave both five - and six-membered ring radicals.Keywords
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