Palladium-Catalyzed Coupling Reaction of Salicylaldehydes with Aryl Iodides via Cleavage of the Aldehyde C–H Bond
- 1 September 1996
- journal article
- research article
- Published by Oxford University Press (OUP) in Chemistry Letters
- Vol. 25 (9) , 823-824
- https://doi.org/10.1246/cl.1996.823
Abstract
It has been found that the cross-coupling reaction of salicylaldehydes with aryl iodides smoothly proceeds by using a catalyst system of PdCl2/LiCl in the presence of Na2CO3 as base to give the corresponding 2-aroylphenols in good yields, which appears to involve cleavage of the aldehyde C–H bond.Keywords
This publication has 16 references indexed in Scilit:
- Asymmetric Catalysis. Asymmetric Catalytic Intramolecular Hydroacylation of 4-Pentenals Using Chiral Rhodium Diphosphine CatalystsJournal of the American Chemical Society, 1994
- Palladium‐Catalyzed C-H Activation oftert‐Butyl Groups: A Simple Synthesis of 1,2‐Dihydrocyclobutabenzene DerivativesAngewandte Chemie International Edition in English, 1994
- Catalytic and regioselective acylation of aromatic heterocycles using carbon monoxide and olefinsJournal of the American Chemical Society, 1992
- Mechanisms of intramolecular activation of carbon-hydrogen bonds in transition-metal complexesChemical Reviews, 1990
- Ruthenium complex catalyzed intermolecular hydroacylation and transhydroformylation of olefins with aldehydesThe Journal of Organic Chemistry, 1990
- Zirconium-catalyzed coupling of propene and .alpha.-picolineJournal of the American Chemical Society, 1989
- Transition-metal-catalyzed carbon-carbon bond formation via carbon-hydrogen activation. Intermolecular hydroacylation: the addition of aldehydes to alkenesOrganometallics, 1988
- Carbon-hydrogen bond activation by ruthenium for the catalytic synthesis of indolesJournal of the American Chemical Society, 1986
- Catalytic carbon-carbon bond formation via ortho-metalated complexesJournal of the American Chemical Society, 1986
- Homogeneous catalytic activation of carbon-hydrogen bondsAccounts of Chemical Research, 1975