Steric Control of the Electronic Ground State in Six-Coordinate Copper(II) Complexes
- 4 September 1998
- journal article
- research article
- Published by Wiley in Angewandte Chemie International Edition in English
- Vol. 37 (16) , 2221-2223
- https://doi.org/10.1002/(sici)1521-3773(19980904)37:16<2221::aid-anie2221>3.0.co;2-a
Abstract
Replacing the 3‐ and 3′′‐protons of the ligand 2,6‐di(pyrazol‐1‐yl)pyridine L by mesityl groups changes the electronic ground state of [Cu(L)2]2+ complexes from {d}1 to {d}1. This is the best example so far for a “homoleptic” Jahn–Teller‐compressed six‐coordinate CuII complex.This publication has 0 references indexed in Scilit: