The tetranuclear cluster Fe III [Fe III (salicylhydroximato)(MeOH)(acetate)]3 is an analogue of M3+(9-crown-3)
- 1 January 1989
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 21,p. 1606-1608
- https://doi.org/10.1039/c39890001606
Abstract
The first example of transition metal co-ordination to ethereal like oxygens of a 9-metallocrown-3 ether is seen in FeIII[FeIII(salicylhydroximato)(MeOH)(acetate)]3 and leads to an unusual tetranuclear cluster which exhibits both inter- and intra-cluster antiferromagnetic interactions and an S= 5 ground state.Keywords
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