Oxidative conversion of β-hydroxyselenides to epoxides and ketones with meta-chloroperbenzoic acid
- 1 January 1988
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 2,p. 111-112
- https://doi.org/10.1039/c39880000111
Abstract
Treatment of β-hydroxy-primary-alkyl and β-hydroxy-β-phenyl-primary-alkyl selenides with 3–5 equiv. of meta-chloroperbenzoic acid in methanol or tetrahydrofuran gives the corresponding epoxides and phenyl migrated ketones, respectively, in high yields.Keywords
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