Oxidation of chiral 9-fluorinated substrates by castor stearoyl-ACP Δ9 desaturase yields novel products

3 April 2001

journal article
research article
Published by Royal Society of Chemistry (RSC) in Chemical Communications

No. 8,p. 765-766
https://doi.org/10.1039/b100035g

Abstract

Desaturation of (S)-9-fluorostearoyl-ACP using stearoyl-ACP Δ⁹ desaturase yielded mainly (E)-9-fluoroalk-9-enic product, while desaturation of (R)-9-fluorostearoyl-ACP gave the novel (Z)-9-fluoroalk-9-ene and (Z)-9-fluoroalk-10-ene.

Keywords

DESATURASE YIELDS
Δ9 DESATURASE
STEAROYL ACP
ACP Δ9
FLUORINATED
CASTOR
CHIRAL
ENIC
GAVE

This publication has 0 references indexed in Scilit: