Friedel-Crafts Reaction of 1,3,5-Trialkylbenzenes with Sulfur Monochloride and N-Chlorodimethylamine
- 1 September 1975
- journal article
- Published by Oxford University Press (OUP) in Bulletin of the Chemical Society of Japan
- Vol. 48 (9) , 2607-2608
- https://doi.org/10.1246/bcsj.48.2607
Abstract
The reaction of sulfur monochloride gave 2,4,6-tri-t-butylchlorobenzene (3) from 1,3,5-tri-t-butylbenzene (1), but gave the corresponding sulfide and disulfide from mesitylene (2). The reaction of N-chlorodimethylamine gave 3, 2-chloro-3,5-di-t-butyltoluene and 2,4,6-trimethylchlorobenzene from 1, 3,5-di-t-butyltoluene and 2, respectively. The reaction of N-chlorodimethylamine with benzene gave chlorobenzene or N,N-dimethylaniline in 1-nitropropane or nitromethane.This publication has 7 references indexed in Scilit:
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