The crystal structure of bis(μ-trichloroacetato-O,O′)-bis[dimethyltin(IV)] and its relationship to other (μ-acetato derivatives
- 1 April 1982
- journal article
- Published by Canadian Science Publishing in Canadian Journal of Chemistry
- Vol. 60 (7) , 934-938
- https://doi.org/10.1139/v82-140
Abstract
The X-ray crystal structre of bis(μ-trichloroacetato-O,O′)-bis[dimethyltin(IV)] has been determined: R′ = 0.0518. The crystals were monoclinic, space group P2/c, a = 10.223(3) Å, b = 7.539(2) Å, c = 12.711(4) Å, β = 97.76(2) and Z = 2. The molecular structure consists of a planar (CH3)2Sn—Sn(CH3)2 unit with the tin atoms bridged asymmetrically by two trichloroacetato groups to give each tin atom five coordination.Keywords
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