Magnetic Properties of Molybdenum(IV) Trinuclear Coordination Compounds, Ba[Mo3O3S(Hnta)3]·10H2O and Cai1.5[Mo3S4(Hnta)2(nta)]·12H2O
- 1 March 1990
- journal article
- Published by Oxford University Press (OUP) in Bulletin of the Chemical Society of Japan
- Vol. 63 (3) , 799-803
- https://doi.org/10.1246/bcsj.63.799
Abstract
The magnetic susceptibilities of two molybdenum(IV) trinuclear coordination compounds with cores [Mo3(μ3-S)(μ-O)3] and [Mo3(μ3-S)(μ-S)3] were measured in the temperature region from liquid He to room temperature. They had some extra diamagnetic susceptibilities in addition to the calculated values which have been discussed in anticipation of mesoscopic electronic devices.Keywords
This publication has 19 references indexed in Scilit:
- Preparation of trinuclear molybdenum(IV) ion, Mo3S4+4, and x-ray structure of Ca[Mo3S4 {HN(CH2CO2)2}3] · 11.5H2OPolyhedron, 1986
- Electronic Structure of the Superatom: A Quasiatomic System Based on a Semiconductor HeterostructurePhysical Review Letters, 1986
- Sulfur capped trinuclear molybdenum(IV) ion, Mo3O3S4+Journal of the American Chemical Society, 1984
- Temperature Dependence of Magnetic Susceptibilities of (TTT)(TCNQ) and (TTT)(TCNQ)2Bulletin of the Chemical Society of Japan, 1984
- Applications of molybdenum-95 NMR spectroscopy. 7. Studies of metal-metal bonded systems including aqueous molybdenum(IV) and molybdenum(V). Crystal and molecular structure of Na2[Mo3O4((O2CCH2)2NCH3)3].7H2OJournal of the American Chemical Society, 1983
- MoIV in Aqueous Solutions: The Trinuclear Cluster [MoIVO4F9]5−, the First Species Isolated from Mineral Acid SolutionAngewandte Chemie International Edition in English, 1981
- Activation and Sulfur‐Atom Transfer Reaction of Cluster‐Bonded S‐Bridge Ligands: Synthesis of the New Cluster [MoS4(CN)9]5− from [MoS(S2)6]2− and CN−Angewandte Chemie International Edition in English, 1980
- An EDTA complex containing two triangular trimolybdenum clusters with molybdenum-molybdenum single bondsJournal of the American Chemical Society, 1979
- A trinuclear molybdenum(IV) cluster compound having an unusual structure and unusual stabilityJournal of the American Chemical Society, 1978
- Di-.mu.-oxo, .mu.-oxo-.mu.-sulfido, and di-.mu.-sulfido complexes of molybdenum(V) with EDTA, cysteine, and cysteine ester ligands. Preparation and electrochemical and spectral propertiesInorganic Chemistry, 1977