Universal transport coefficient behaviour in ionic melts
- 27 October 1999
- journal article
- Published by IOP Publishing in Journal of Physics: Condensed Matter
- Vol. 11 (45) , 8773-8784
- https://doi.org/10.1088/0953-8984/11/45/302
Abstract
Precise resistivity and viscosity measurements for ionic mixed melts, regular and glass-forming, have been performed on the liquid state over a wide range of viscosity variation. Their universal behaviour in the high-temperature region allows us to scale them relative to their activation energy. The resistivity-viscosity relation reveals a fractional-power character over the whole range of parameters investigated. This interdependence suggests a fractional character of the Stokes-Einstein law of the viscosity-diffusion relation for ions in melts.Keywords
This publication has 39 references indexed in Scilit:
- Dynamics of highly supercooled liquids: Heterogeneity, rheology, and diffusionPhysical Review E, 1998
- Evidence of a fractional Debye-Stokes-Einstein law in supercooled o-terphenylEurophysics Letters, 1997
- Domain-Wall Scaling Study of the Structural Glass TransitionPhysical Review Letters, 1996
- Frustration-limited clusters in liquidsThe Journal of Chemical Physics, 1994
- Temperature dependence of characteristic length for glass transitionPhysical Review Letters, 1992
- The dynamics of binary mixtures of nonpolymeric viscoelastic liquids as studied by quasielastic light scatteringThe Journal of Chemical Physics, 1990
- Atomic test of the Stokes-Einstein law. II. Diffusion of Xe through liquid hydrocarbonsPhysical Review A, 1985
- Inadequacies of Viscosity Theories for a Vitreous KNO3-Ca(NO3)2 MeltJournal of the American Ceramic Society, 1971
- Viscosity of a vitreous potassium nitrate - calcium nitrate mixtureThe Journal of Physical Chemistry, 1969
- Berechnung verschiedener physikalischer Konstanten von heterogenen Substanzen. I. Dielektrizitätskonstanten und Leitfähigkeiten der Mischkörper aus isotropen SubstanzenAnnalen der Physik, 1935