High-performance liquid chromatography–electron spin resonance analysis of sugars irradiated in the solid and liquid phase
- 1 January 1987
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Faraday Transactions 1: Physical Chemistry in Condensed Phases
- Vol. 83 (1) , 225-230
- https://doi.org/10.1039/f19878300225
Abstract
Radicals, produced by γ-irradiation of sugars in the solid state at different temperatures and in aqueous solution, have been studied by the spintrapping method. High-performance liquid chromatography has been used to separate the nitroxides formed and hence simplify the total observed electron spin resonance spectra. Several correlations between radicals formed in α-and β-glucose, methyl-l-α-glucose, maltose, sucrose and related compounds are presented.Keywords
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