Regioselective Formation of C-Centered Radicals Using the Intramolecular 1,5-Hydrogen Atom Transfer

1 January 1991

journal article
letter
Published by Georg Thieme Verlag KG in Synlett

Vol. 1991 (09) , 621-624
https://doi.org/10.1055/s-1991-20817

Abstract

A regioselective method for the formation of C-centered radicals using an intramolecular 1,5-hydrogen atom transfer from a C(sp³)-H bond to an aryl radical is described. The efficiency of the process depends on conformational effects rather than on the stabilization of the final radical by the adjacent substituents.

Keywords

CENTERED RADICALS
HYDROGEN ATOM
RADICALS USING
INTRAMOLECULAR
ATOM TRANSFER
SUP
CONFORMATIONAL EFFECTS
REGIOSELECTIVE METHOD

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