Borverbindungen, 8. Mitteilung Umlagerung mittlerer O-B-O-Heterocyclen zu ringförmigen Oligomeren / Boron Compounds, Part 8 Rearrangement of Medium Sized O-B-O Heterocycles to Cyclic Oligomers
Open Access
- 1 December 1977
- journal article
- Published by Walter de Gruyter GmbH in Zeitschrift für Naturforschung B
- Vol. 32 (12) , 1408-1415
- https://doi.org/10.1515/znb-1977-1210
Abstract
The condensation of phenyldihydroxyborane with pentane-1,5-diols yields no 1,3,2-dioxabora-cyclooctanes but oligomeric boron heterocycles. Their formation can be explained by an exchange of ligands of the boron atom, a process analogous to metathetic ring-opening polymerisation.Keywords
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