Homogeneous catalytic activation of C–N bonds. Alkyl exchange between tertiary amines
- 1 January 1980
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 16,p. 753-754
- https://doi.org/10.1039/c39800000753
Abstract
We have found that several transition metal cluster compounds act as homogeneous catalyst precursors in alkyl exchange reactions of tertiary amines; treatment of mixtures of Et3N and Pr3N with either Ru3(CO)12, Os3(CO)12, or Ir4(CO)12 and water leads to very efficient alkyl exchange.Keywords
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