The preparation and crystal structure of cis-bis(trimethylsilylsulphurdiimido)bis(triphenylphosphine)platinum(II)
- 1 January 1985
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 4,p. 227-228
- https://doi.org/10.1039/c39850000227
Abstract
Reaction of (η2-ethene)bis(triphenylphosphine)platinum(0) with bis(trimethylsilyl)sulphurdiimide yields cis-[Pt(NSNSiMe3)2(PPh3)2]the first example of a complex containing the RNSN– ligand, in this case sigma bonded to platinum via nitrogen.Keywords
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