A high ratio hydrido-metal cluster: synthesis and X-ray crystal structure of [Pt5H8(PBut 2Ph)5]
- 1 January 1981
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 14,p. 716-717
- https://doi.org/10.1039/c39810000716
Abstract
Reaction of [Pt(C2H4)2(PBut 2Ph)] with hydrogen affords [Pt5H8(PBu2tPh)5] which has a distorted trigonal bipyramidal solid-state structure and time-averaged D3h symmetry in solution, with two terminal and six bridging hydride ligands.Keywords
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