2Eg→4A2gTransition of the hexa-amminochromium(III) ion in cubic environments. Intensity mechanism and Jahn-Teller effect
- 1 January 1972
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Faraday Transactions 2: Molecular and Chemical Physics
- Vol. 68, 897-904
- https://doi.org/10.1039/f29726800897
Abstract
The 2Eg→4A2g phosphorescence of a series of carefully purified salts containing the Cr(NH3)3+ 6 ion has been measured from 300 to 4 K. All seven τ1u and two of the τ2u fundamentals act as vibronic origins and the first members of progressions in the εg modes are observed. This is evidence for a Jahn-Teller effect in the 4T2g state.Keywords
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