Transmetallation Between Vinylic Tellurides and Higher Order Cyanocuprates: In Situ Formation of Vinyl Cuprates
- 1 June 1990
- journal article
- research article
- Published by Taylor & Francis in Synthetic Communications
- Vol. 20 (11) , 1681-1685
- https://doi.org/10.1080/00397919008053089
Abstract
Vinylic tellurides react with higher order dialkylcyanocuprates leading to mixed vinylcyanocuprates with retention of the olefin geometry. The mixed vinylcyanocuprates react with enones giving the 1,4-addition products in good yields.Keywords
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