Grafting of Vinyudene Chloride. Model Studies with Poly(Vinyl Alcohol) as Substrate
- 1 September 1987
- journal article
- research article
- Published by Taylor & Francis in Journal of Macromolecular Science: Part A - Chemistry
- Vol. 24 (9) , 1051-1064
- https://doi.org/10.1080/00222338708078142
Abstract
The modification of coatings resins by graft polymerization of vinylidene chloride should produce a coatings binder with improved barrier properties. For superior color stability, vinylidene chloride must be copolymer-ized with other monomers such as alkyl acrylates and methacrylates. Ceric ion initiation was used to graft vinylidene chloride free-radically onto a model alcohol-containing polymer, polyvinyl alcohol. The effects of various reaction parameters on vinylidene chloride grafting were studied. Graft copolymers were characterized using selective solvent extraction, FTIR, SEM, XES, DSC, and x-ray diffraction.Keywords
This publication has 7 references indexed in Scilit:
- Homogeneous Graft Copolymerization of Vinyl Monomers onto Cellulose in a Dimethyl Sulfoxide–Paraformaldehyde Solvent System III. Methyl AcrylatePolymer Journal, 1983
- Redox Polymerization Initiated by Metal IonsJournal of Macromolecular Science, Part C: Polymer Reviews, 1980
- Grafting of methyl methacrylate to nitrocellulose by ceric ionsJournal of Applied Polymer Science, 1979
- Effect of amines on the ceric ion‐initiated polymerization of vinyl monomers. I. Polymerization of acrylonitrile by ceric ion–triethylamine catalyst systemJournal of Polymer Science Part A-1: Polymer Chemistry, 1971
- Polymerization of vinyl monomersProceedings of the Indian Academy of Sciences - Section A, 1965
- The polymerization of acrylamide initiated by ceric nitrate‐3‐chloro‐1‐propanol redox systemsJournal of Polymer Science, 1959
- Unit cell dimensions of polyvinylidene chloride and polyvinylidene bromideJournal of Polymer Science, 1959