Hydroformylation of hex-1-ene in supercritical carbon dioxide catalysed by rhodium trialkylphosphine complexes
- 1 January 1998
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Chemical Communications
- No. 14,p. 1463-1464
- https://doi.org/10.1039/a803855d
Abstract
Triethylphosphine complexes of rhodium catalyse the hydroformylation of hex-1-ene in supercritical carbon dioxide at rates similar to those obtained in toluene, but with a slightly improved n:i ratio; using trioctylphosphine, much lower rates are observed.Keywords
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