Estimation of the combustion products from the cylinder of the petrol engine and its relation to "knock"

Abstract
As a result of a variety of experiments it was suggested in 1928 that engine “knock” “appears to be due to inequality in the condition of the charge (in the engine cylinder) set up, particularly in regions of high pressure and temperature as in the neighbourhood of hot exhaust valves. This inequality provides regions of high energy containing molecules in high energy states where reaction can spread more quickly.” This view was a little vague, and was arrived at from indirect experimental evidence. It was with a view to obtaining more precise evidence that knock was occasioned in the flame as the result of processes of slow combustion occurring in the gaseous charge prior to its arrival that the present work was undertaken. Callendar and those working with him had simultaneously arrived at the conclusion that “knock” was occasioned in much the same manner, but they adopted the more definite view that peroxides of the hydrocarbons were formed and stored in the gas, and then suddenly detonated, so igniting a whole region of the gas simultaneously. This view had also been advanced by Moureu and Dufraisse.

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