5, 10, 15, 20‐Tetra‐tert‐butylporphyrin und seine bemerkenswerte Reaktivität in 5, 15‐Stellung
- 16 January 1994
- journal article
- zuschrift
- Published by Wiley in Angewandte Chemie
- Vol. 106 (18) , 1951-1953
- https://doi.org/10.1002/ange.19941061823
Abstract
Wegen des Raumbedarfs der tert‐Butylgruppen weicht die Reaktivität des neuartigen Porphyrins 1 mit nichtplanarem makrocyclischem Grundgerüst von der aller bekannten Porphyrine ab. So führt längere Behandlung von 1 mit HClO4/MeOH zur Bildung des 5,15‐Dihydroporphyrins (“Porphodimethens”) 2. magnified imageKeywords
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