SYNTHESIS OF [2,2] FERROCENOPHANE-1,13-DIENE
- 5 January 1978
- journal article
- Published by Oxford University Press (OUP) in Chemistry Letters
- Vol. 7 (1) , 21-24
- https://doi.org/10.1246/cl.1978.21
Abstract
[2,2] Ferrocenophane-1,13-diene (1) was synthesized via the intermolecular coupling of ferrocene-1,1′-dicarbaldehyde (2) with TiCl4–LiAlH4. The catalytic hydrogenation of 1 led to the formation of [2,2] ferrocenophane (7). An alternate approach to the synthesis of 7, involving the reductive coupling of 1,1′-bis(hydroxymethyl)ferrocene with TiCl4–LiAlH4 is described.This publication has 13 references indexed in Scilit:
- FerrocenophanesRussian Chemical Reviews, 1974
- Preparation of metallocenes from hydrocarbon dianionsJournal of the American Chemical Society, 1973
- The Carbonylation of 1,1′-Bis(chloromercuri)ferrocene with Palladium Salt: A Synthesis of [1.1]Ferrocenophane-1,12-dioneBulletin of the Chemical Society of Japan, 1972
- Synthesis of [2.2]ferrocenophane-1,13-diyneJournal of Organometallic Chemistry, 1970
- Organometallic .pi. complexes of fulvaleneJournal of the American Chemical Society, 1969
- Synthesis of 1,1'-biferrocenyleneJournal of the American Chemical Society, 1969
- Bridged ferrocenes—VITetrahedron, 1969
- The Friedel—Crafts route to the [1.1]ferrocenophane systemJournal of Organometallic Chemistry, 1967
- The [1,1]Ferrocenophane System1Journal of the American Chemical Society, 1966
- The as-Indacenyl Dianion and Bis(as-indacenyliron)Journal of the American Chemical Society, 1964