Low‐pressure granulite facies metapelitic assemblages and corona textures from MacRobertson Land, east Antarctica: the importance of Fe2O3 and TiO2 in accounting for spinel‐bearing assemblages

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Abstract
Low‐pressure granulite facies metasedimentary gneisses exposed in MacRobertson Land, east Antarctica, include hercynitic spinel‐bearing metapelitic gneisses. Peak metamorphic mineral assemblages include spinel + rutile + ilmenite + sillimanite + garnet, spinel + ilmenite + sillimanite + garnet + cordierite, ortho‐pyroxene + magnetite + ilmenite + garnet, spinel + cordierite + biotite + ilmenite and orthopyroxene + cordierite + biotite, each with quartz, K‐feldspar and melt. The presence of garnet + biotite‐ and cordierite + orthopyroxene‐bearing assemblages implies crossing tie‐lines in AFM projection for the K2O‐FeO‐MgO‐Al2O3‐SiO2‐H2O (KFMASH) system. This apparent contradiction, and the presence of spinel, rutile and ilmenite in the assemblages, is acounted for by using the KFMASH‐TiO2‐O2 system, i.e. AFM + TiO2+ Fe2O3. We derive a petrogenetic grid for this system, applicable to low‐pressure granulite facies metamorphic conditions. Retrograde assemblages are interpreted from corona textures on hercynitic spinel and Fe‐Ti oxides. The relative positions of the peak and retrograde metamorphic assemblages on the petrogenetic grid suggest that corona development occurred during essentially isobaric cooling.