Some η1and η3-allylic and metallocyclobutane derivatives of molybdenum and tungsten
- 1 January 1976
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 16,p. 619-621
- https://doi.org/10.1039/c39760000619
Abstract
Nucleophilic attack by R–= H– or Me– on [W(η5-C5H5)2(η3-CH2CHCH2)]+PF6 – occurs on the central carbon of the η3-allylic group giving the metallocyclobutane compounds [W(η5-C5H5)2(CH2CHRCH2)] which, for RH, undergo deuteriation giving [W(η5-C5H5)2H(CH2CHCH2D)]+PF6 –; similar attack occurs on the analogous molybdenum compounds.Keywords
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