Asymmetric self-assembly with atmospheric CO2fixation of a pentanuclear carbonate NiIIcomplex based on dissimilar building blocks

Abstract
Formation in basic solution of an asymmetric pentanuclear carbonate NiII complex with a compartmental ligand involves atmospheric CO2 uptake, either by reaction of two slightly different dinuclear precursors that yield its di- and trinuclear “building blocks”, or directly, by spontaneous self-organization of metal and ligand starting reactants.

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