Isomerism of the Metal Complexes containing Multidentate Ligands. I. Geometric and Optical Isomers of the Bis(diethylenetriamine)-cobalt(III) Ion
- 1 January 1972
- journal article
- Published by Oxford University Press (OUP) in Bulletin of the Chemical Society of Japan
- Vol. 45 (1) , 179-184
- https://doi.org/10.1246/bcsj.45.179
Abstract
Three possible isomers of bis(diethylenetriamine)cobalt(III) halide were isolated by column chromatography on ion-exchange cellulose and Sephadex, and the mer- and u-facial isomers were completely resolved by column chromatography on SE-Sephadex. These isomers were studied by electronic, infrared, and PMR spectroscopy, and the absolute configuration of the u-facial isomer was assigned on the basis of the circular dichroism spectrum.This publication has 23 references indexed in Scilit:
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