Sterically Crowded Sulfonate Esters: Novel Leaving Groups with Hindered S-O Cleavage
- 1 January 1987
- journal article
- research article
- Published by Georg Thieme Verlag KG in Synthesis
- Vol. 1987 (08) , 683-688
- https://doi.org/10.1055/s-1987-28045
Abstract
Reagents and procedures for the preparation of tert-butyl sulfonate esters 2 and 2,2,2-trifluoro-1,1-diphenylethane sulfonate esters 3 (TDE-sulfonates) are described. In these new sulfonates, S-O-scission is reduced significantly by steric hindrance.Keywords
This publication has 0 references indexed in Scilit: