Regiospecific synthesis of terminal, oxyfunctionalized methyl ketone enamines via catalytic aminomercuriation of prop-2-ynyl esters and ethers
- 1 January 1986
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 19,p. 1465-1467
- https://doi.org/10.1039/c39860001465
Abstract
Catalytic aminomercuriation of 1-substituted prop-2-ynyl esters and ethers (5) provides a mild, simple, and regiospecific route to the terminal functionalized enamines (6) despite the fact that they are potentially isomerisable to their internal form; hydrolysis of (6) furnishes α-oxyketones (7).Keywords
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