Spin Densities in Dimesitylmethyl
- 1 May 1960
- journal article
- conference paper
- Published by AIP Publishing in The Journal of Chemical Physics
- Vol. 32 (5) , 1488-1489
- https://doi.org/10.1063/1.1730946
Abstract
A simple valence bond calculation indicates that if the dimesitylmethyl radical were planar large unpaired spin densities would appear on the ring methyl groups giving a spectrum about 130 gauss wide. A perturbation calculation, assuming that the molecule is very twisted, gives spin densities ρ1=1.000, ρ2=—0.069, ρ3=0.054, ρ4=—0.040, ρ5=0.043 on the carbon atoms, numbered from the center outwards.Keywords
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