Effects of metal ions on rates of detritiation–new probe in the study of metal–substrate interactions
- 1 January 1975
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 20,p. 856
- https://doi.org/10.1039/c39750000856
Abstract
The rate retarding effect of metal ions (Cu2+ > Zn2+ Ni2+ > > MeHg+) on isotopic hydrogen exchange from the C(2) position of imidazole can be rationalised in terms of complex formation; the stability constants can be evaluated from the exchange rate constants.Keywords
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