Feasibility Study of Raman Spectroscopy as a Tool to Investigate the Liquid-Phase Chemistry of Aliphatic Organic Peroxides
- 1 January 1997
- journal article
- Published by SAGE Publications in Applied Spectroscopy
- Vol. 51 (1) , 74-80
- https://doi.org/10.1366/0003702971938795
Abstract
The described investigations are focused on peroxides occurring as products in atmospheric chemical processes, namely, hydrogen peroxide, methylhydroperoxide, hydroxymethylhydroperoxide, bis-(hydroxymethyl)peroxide, 1-hydroxyethylhydroperoxide, bis-(hydroxyethyl)peroxide, and hydroxymethylmethylperoxide. The compounds are identified and determined through the position and intensity of their characteristic O–O stretching bands in the range between 767 and 878 cm−1. Time-resolved Raman spectroscopy of peroxide solutions permits the in situ investigation of pathways and kinetics of reactions between peroxides and aldehydes.Keywords
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