Cyclopropenschemie, VI.Cyclopropenone Chemistry, VI.
Open Access
- 1 June 1975
- journal article
- Published by Walter de Gruyter GmbH in Zeitschrift für Naturforschung B
- Vol. 30 (5-6) , 404-408
- https://doi.org/10.1515/znb-1975-5-620
Abstract
The synthesis of methyl-phenylcyclopropenone (1 a) is decribed. Bromination of this and of diphenylcyclopropenone yields saltlike complexes 2 which are in equilibrium with their components. Di-n-propylcyclopropenone and bromine give the ring opened product 3d. la and N-bromosuccinimid give 4 and 5, phenyl brominated derivatives, in sulfuric acid. With cupric bromide substituted β-bromoacrylic acids are formed along with cyclopropenone dimers (7).Keywords
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