The electron spin resonance spectrum and spin density distribution of the benzyl radical
- 1 January 1965
- journal article
- research article
- Published by Taylor & Francis in Molecular Physics
- Vol. 9 (2) , 137-147
- https://doi.org/10.1080/00268976500100151
Abstract
The benzyl radical has been generated in aqueous solution by means of a continuous flow system. The electron spin resonance spectrum is almost completely resolved, and accurate values for the four proton hyperfine splittings are obtained. The spin density distribution in the benzyl radical is calculated by various methods and the relationship between theoretical spin densities and proton hyperfine constants is studied.Keywords
This publication has 33 references indexed in Scilit:
- Second Moments of Electron Spin Resonance Proton Hyperfine SpectraThe Journal of Chemical Physics, 1963
- Hyperfine coupling constants and their dependence on charge densitiesMolecular Physics, 1963
- 572. Electron spin resonance studies of oxidation. Part I. AlcoholsJournal of the Chemical Society, 1963
- Chemical Preparation and Electron Spin Resonance Spectra of Specific Trapped Hydrocarbon RadicalsNature, 1962
- Theory of Isotropic Hyperfine Interactions in π-Electron RadicalsThe Journal of Chemical Physics, 1958
- On the Interpretation of the Electron Spin Resonance Spectra of Solutions of Hydrocarbons in Sulfuric AcidThe Journal of Chemical Physics, 1957
- Die Elektronenstruktur und Lichtabsorption des BenzylradikalsZeitschrift für Naturforschung A, 1955
- Primary photochemical processes in aromatic molecules. Part 3. Absorption spectra of benzyl, anilino, phenoxy and related free radicalsTransactions of the Faraday Society, 1955
- Lack of Resonance Energy in Gaseous Carbonium IonsThe Journal of Chemical Physics, 1951
- The C–H Bond Energy in Toluene and XylenesThe Journal of Chemical Physics, 1948