Fixed bed desorption behavior of gases with non‐linear equilibria: Part I. Dilute, one component, isothermal systems

Abstract
Generalized depletion curves for desorption (and breakthrough curves for adsorption) were calculated for a system characterized by the Langmuirtype equilibria and controlled by a film type rate model. The depletion points generally appear sooner than the corresponding breakthrough points, and the desorption profiles are significantly broader than the corresponding adsorption curves. These phenomena may be best explained in terms of the prevailing driving forces. The effects of adsorbate properties and operating variables (inlet composition and flow rate) were established and experimentally substantiated.

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