Stereospecificity in radical carbon–carbon bond formation reactions based on tartaric acid
- 1 January 1987
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 23,p. 1790-1792
- https://doi.org/10.1039/c39870001790
Abstract
Radical decarboxylative addition to activated alkenes, using the thiohydroxamic ester method, of a suitably protected derivative of (+)-L-tartaric acid leads to overall substitution of the carboxy group with essentially complete retention of configuration.Keywords
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