Evaluation of Coefficients for the Weighted Sum of Gray Gases Model

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Abstract
The weighted sum of gray gases model postulates that total emissivity and absorptivity may be represented by the sum of a gray gas emissivity weighted with a temperature dependent factor. The gray gas emissivity is expressed in terms of a temperature-independent absorption coefficient, absorbing gas partial pressure, and path length. The weighting factors are given by polynomials in gas temperature with associated polynomial coefficients. For absorptivity, a second polynomial for the irradiation temperature is introduced. A regression scheme is employed to fit the model to total emissivity and absorptivity values obtained from the exponential wide-band model. Absorption and polynomial coefficients are reported for carbon dioxide, water vapor, and mixtures of these gases. The model with these coefficients more accurately represents the total properties over a wider range of temperatures and partial pressure-path length products than previously available coefficients.

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