The relative inhibitory effect of various compounds on the rate of polymerization of vinyl acetate
- 1 March 1961
- journal article
- research article
- Published by Wiley in Journal of Applied Polymer Science
- Vol. 5 (14) , 212-217
- https://doi.org/10.1002/app.1961.070051414
Abstract
The relative inhibitory effects of acetaldehyde, acetone, 1‐acetoxy‐1,3‐butadiene, benzene, 1,3‐butadienylacetylene, carbon disulfide, crotonaldehyde, diacetyl, diacetylene, divinylacetylene, divinyl sulfide, 1,3,5‐hexatriene, monovinylacetylene, thiophene, and toluene on the bulk polymerization of vinyl acetate were measured. Two polymerization tests utilizing different concentrations of benzoyl peroxide catalyst were used. Experimental details of the tests, inhibition factors and curves, and general conclusions regarding the magnitude of the inhibition caused by various organic functional groups are given.Keywords
This publication has 17 references indexed in Scilit:
- A New Preparation of 1,3,5-Hexatriene and the Separation of its Geometrical IsomersJournal of the American Chemical Society, 1960
- DIACETYLENE: PREPARATION, PURIFICATION, AND ULTRAVIOLET SPECTRUMCanadian Journal of Chemistry, 1958
- Dye-sensitized Photopolymerization of Acrylamide1Journal of the American Chemical Society, 1957
- Some copolymerizations of cis- and trans-DibenzoylethyleneJournal of Polymer Science, 1955
- The interaction of polymerizing systems with rubber and its homologues. Part 3.—Transfer and retardation in the polymerization of vinyl acetateTransactions of the Faraday Society, 1955
- Acetylene Polymers: Preparation, Physical Properties, Infrared and Ultraviolet. Spectra1Journal of the American Chemical Society, 1954
- The interaction of polymerizing systems with rubber and its homologues. Part 1.—The effect of dihydromyrcene on the polymerization of styrene, methyl methacrylate, methyl acrylate and vinyl acetateTransactions of the Faraday Society, 1954
- Dilatometric Studies of the Behavior of Some Inhibitors and Retarders in the Polymerization of Liquid Vinyl Acetate. IJournal of the American Chemical Society, 1950
- Syntheses of Polyenes. I. Hexatriene and its PolymersJournal of the American Chemical Society, 1939
- Synthetische Darstellung von ThiophenEuropean Journal of Inorganic Chemistry, 1885