Oxidative addition reactions of cationic five-co-ordinate iridium(I) complexes of the type [Ir(CO)x(PMe2Ph)5-x]+
- 1 January 1970
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in J. Chem. Soc. A
- p. 3356-3358
- https://doi.org/10.1039/j19700003356
Abstract
Oxidative addition reactions of cationic iridium(I) complexes of the type [Ir(CO)x(PMe2Ph)5-x]+, where x= 2 or 3, with hydrogen halides, hydrogen, chlorine, methyl halides, 2-methylallyl chloride, or mercury(II) halides have been studied. In most cases the stereochemistry of the product was determined by use of 1H n.m.r. and i.r. spectroscopy.Keywords
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