Aromatic hydroxylation: the direct oxidation of C–Pd into C–OPd
- 1 January 1984
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 15,p. 999-1000
- https://doi.org/10.1039/c39840000999
Abstract
The C–Pd bond in cyclopalladated azobenzenes [(1) and (3)] is converted into the C–OPd function [(2) and (5)] in good yield by stoicheiometric reactions with m-chloroperbenzoic acid; in effect azobenzene is successively oxidised to 2-hydroxyazobenzene and 2,2′-hydroxyazobenzene.Keywords
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