Preparation of Tributylstannylmanganate and its Addition to Propargylic Alcohols with High Regio- and Stereoselectivities
- 1 September 1999
- journal article
- letter
- Published by Georg Thieme Verlag KG in Synlett
- Vol. 1999 (9) , 1417-1419
- https://doi.org/10.1055/s-1999-2873
Abstract
A new method has been developed for generating stannylmanganate in a one-flask operation by treatment of Bu3Sn-SnBu3 with Me4MnLi2 or Me3MnLi. These reagents selectively deliver the Bu3Sn moiety to a variety of organic substrates and show unique steroselective trans-addition behaviour to propargylic alcohols.Keywords
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