Cleavage of the P–C bond in [PtCl2(Ph2PCH2PPh2-P,P′)] under mild conditions
- 1 January 1987
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 4,p. 235-236
- https://doi.org/10.1039/c39870000235
Abstract
Treatment of [PtCl2PCH2PPh2-P,P′)] with an excess of NaOH in NH3 at –50 °C gives, in >80% yield, the cis and trans isomers of [(Ph2MeP)(Ph2PO)Pt(µ-NH2)2Pt((POPh2)(PMePh2)], the structure of the trans from being confirmed by X-ray crysallography; both the structure and the proposed mechanism display highly novel features.Keywords
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