Effect of wavelength on the photolysis of p-cyanophenyl azide in dimethylamine
- 1 January 1973
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 11,p. 360-361
- https://doi.org/10.1039/c39730000360
Abstract
The ratio of products, 2-(4-cyanophenyl)-1,1-dimethylhydrazine (I) and 5-cyano-2-dimethyl-3H-azepine (II), which is obtained from the photolysis of p-cyanophenyl azide in dimethylamine is wavelength dependent; this wavelength effect is rationalized in terms of excess of excitation energy producing a hot nitrene.Keywords
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