Synthetic routes to amino sugars. Efficient syntheses of 4-amino- and 4,6-diamino-hexopyranosides and forosamine via hex-2-enopyranosides

Abstract
4-Amino- and 4,6-diamino-hexopyranosides of the threo- and erythro-series have been synthesized from D-glucose via hex-2-enopyranosides. Further work along these lines led to an effective synthesis of forosamine, a 4-deoxy-4-amino sugar moiety of the spiramycin antibiotics.

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