Effect of Lattice Dynamics on Intramolecular Electron-Transfer Rates in Mixed-Valence Complexes
- 1 November 1985
- journal article
- research article
- Published by Taylor & Francis in Comments on Inorganic Chemistry
- Vol. 4 (6) , 329-349
- https://doi.org/10.1080/02603598508072271
Abstract
It is shown that the rates of intramolecular electron transfer for mixed-valence complexes in the solid state are not determined only by the electronic and vibronic coupling in the molecular complex. Lattice dynamics associated with the motion of ligands, solvate and counterions, which sometimes are manifested as phase transitions, frequently influence the electron-transfer rate.Keywords
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