Die Formalpotentiale fester Metallhexacyanometallate
- 15 December 1995
- journal article
- zuschrift
- Published by Wiley in Angewandte Chemie
- Vol. 107 (23-24) , 2876-2878
- https://doi.org/10.1002/ange.19951072314
Abstract
Zum ersten Mal liegen die Formalpotentiale einer Serie von festen Metallhexacyanometallaten (M+)nM′[M″(CN)6] vor (M+ Li+, K+, Na+, Rb+, Cs+; M′ Ag, Al, Cd, Co, Cr, Cu, Fe, Ga, In, Mn, Ni, Pb; M″ Cr, Fe, Mn). Es existiert eine lineare Korrelation zwischen dem Ionenpotential ϕ z/reff der stickstoffgebundenen Ionen M′ und den Formalpotentialen der Hexacyanometallat‐Ionen. Diese ist eine Folge der sich mit zunehmender Säure‐Base‐Wechselwirkung verstärkenden π‐Rückbindung zwischen dem Stickstoffatom der Cyanidionen und den Metallionen M′.Keywords
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